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On the Stereochemical Course of Palladium-Catalyzed Cross-Coupling of Allylic Silanolate Salts with Aromatic Bromides
The stereochemical course of palladium-catalyzed cross-coupling reactions of an enantioenriched, α-substituted, allylic silanolate salt with aromatic bromides has been investigated. The allylic silanolate salt was prepared in high geometrical (Z/E, 94:6) and high enantiomeric (94:6 er) purity by a c...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2836786/ https://ncbi.nlm.nih.gov/pubmed/20163185 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910804u |
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