Water induced relaxation of a degenerate vibration of guanidinium using 2D IR echo spectroscopy

The nearly degenerate asymmetric stretch vibrations near 1600 cm(−1) of the guanidinium cation in D-glycerol/D(2)O mixtures having different viscosity were studied by 2D IR photon echo spectroscopy. The polarization dependent photon echo signal shows two separate frequency distributions in the 2D sp...

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Bibliographic Details
Main Authors: Vorobyev, Dmitriy Yu., Kuo, Chun-Hung, Kuroda, Daniel G., Scott, J. Nathan, Vanderkooi, Jane M., Hochstrasser, Robin M.
Format: Artigo
Language:Inglês
Published: 2010
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2835528/
https://ncbi.nlm.nih.gov/pubmed/20143800
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp909531s
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