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Water induced relaxation of a degenerate vibration of guanidinium using 2D IR echo spectroscopy
The nearly degenerate asymmetric stretch vibrations near 1600 cm(−1) of the guanidinium cation in D-glycerol/D(2)O mixtures having different viscosity were studied by 2D IR photon echo spectroscopy. The polarization dependent photon echo signal shows two separate frequency distributions in the 2D sp...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2835528/ https://ncbi.nlm.nih.gov/pubmed/20143800 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp909531s |
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