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A fast ruthenium polypyridine cage complex photoreleases glutamate with visible or IR light in one and two photon regimes

We introduce a new caged glutamate, based in a ruthenium bipyridyl core, that undergoes heterolytic cleavage after irradiation with visible light with wavelengths up to 532 nm, yielding free glutamate in less than 50 ns. Glutamate photorelease occurs also efficiently following two-photon (2P) excita...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Salierno, Marcelo, Marceca, Ernesto, Peterka, Darcy S., Yuste, Rafael, Etchenique, Roberto
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2835317/
https://ncbi.nlm.nih.gov/pubmed/20060592
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2009.12.004
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