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Steroidal Free Radicals as Possible Intermediates in the Biosynthesis of C(19)-△(16)-Steroids

Treatment of deoxycorticosterone with reagents that abstract a hydrogen atom from the C-21-hydroxyl group leads to the formation of androsta-4,16-dien-3-one. In vitro incubations of [1,2-(3)H]deoxycorticosterone with homogenates of boar testis tissue produce the tritiated dienone. This reaction can...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Lippman, Violet, Lieberman, Seymour
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 1970
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Accesso online:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC283423/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/5275374/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.67.4.1754
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