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Nuclear Magnetic Resonance Spectroscopy. A Stereospecific (3)J(CF) Coupling in the Low-Temperature (13)C Nmr Spectrum of 1,1-Difluorocyclohexane

The proton-decoupled (13)C nmr spectrum of 1,1-difluorocyclohexane has been examined at room temperature and at -90°C. There are only minor changes in the one-bond and two-bond carbon-fluorine scalar coupling constants at the lower temperature; however, the triplet observed for C-3 ((3)J(CF) = 4.7 H...

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Publicado en:Proc Natl Acad Sci U S A
Autores principales: Doddrell, David, Charrier, Claude, Roberts, John D.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 1970
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Acceso en línea:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC283406/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16591888/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.67.4.1649
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