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Nuclear Magnetic Resonance Spectroscopy. Variable-Temperature (13)C and (19)F Study of the Chair-Chair Interconversion of 1,1,3,3-Tetramethylcyclohexane and gem-Difluoro-1,1,3,3-Tetramethylcyclohexanes

A variable-temperature, proton noise-decoupled, (13)C nmr spectral study of the chair-chair interconversion in 1,1,3,3-tetramethylcyclohexane has demonstrated the utility of (13)C spectra for probing conformational equilibria. There is a much larger chemical-shift difference between the carbons of a...

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Detalhes bibliográficos
Main Authors: Doddrell, David, Charrier, Claude, Hawkins, Bruce L., Crain, W. O., Harris, Leland, Roberts, John D.
Formato: Artigo
Idioma:Inglês
Publicado em: 1970
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC283394/
https://ncbi.nlm.nih.gov/pubmed/16591886
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