The Anomalous Deuterium Isotope Effect on the Chemical Shift of the Bridge Hydrogen in the Enol Tautomer of 2,4-Pentanedione
The nature of the intramolecular hydrogen bond in the enol tautomer of 2,4-pentanedione has been investigated by high resolution proton and deuteron magnetic resonance spectroscopy. An unusually large deuterium isotope effect on the chemical shift of the bridge hydrogen has been observed. This unexp...
Gardado en:
| Publicado en: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
National Academy of Sciences
1970
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC282988/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16591824/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.65.4.816 |
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