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Arylchlorogermanes/TBAF/“Moist” Toluene. A Promising Combination for Pd-Catalyzed Germyl-Stille Cross-Coupling
[Image: see text] The trichlorophenyl,- dichlorodiphenyl,- and chlorotriphenylgermanes undergo Pd-catalyzed cross-couplings with aryl bromides and iodides in the presence of TBAF in toluene with addition of the measured amount of water. One chloride ligand on the Ge center allows efficient activatio...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2827299/ https://ncbi.nlm.nih.gov/pubmed/20092358 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9028918 |
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