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Indolyne and Aryne Distortions and Nucleophilic Regioselectivites
[Image: see text] DFT computations reproduce the surprisingly high regioselectivities in nucleophilic additions and cycloadditions to 4,5-indolynes, and the low regioselectivities in reactions of 5,6-indolynes. Transition state distortion energies control regioselectivities, activating the 5 and 6 p...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2819077/ https://ncbi.nlm.nih.gov/pubmed/20058924 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9098643 |
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