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The origin of slow relaxation following photoexcitation of W7 in myoglobin and the dynamics of its hydration layer

Molecular dynamics simulations are used to calculate the time dependent Stokes shift following photoexcitation of Trp-7 (W7) in myoglobin. In agreement with experiment, a long time (~60ps) component is observed. Since the long time Stokes shift component is absent when we repeat the calculation with...

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Autors principals: Li, Tanping, Hassanali, Ali A., Singer, Sherwin J.
Format: Artigo
Idioma:Inglês
Publicat: 2008
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2818739/
https://ncbi.nlm.nih.gov/pubmed/19368022
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