Conformational analysis of 9β,19-cyclopropyl sterols: Detection of the pseudoplanar conformer by nuclear Overhauser effects and its functional implications

Nuclear Overhauser difference spectroscopy and variable temperature studies of the 9β,19-cyclopropyl sterols 24,25-dehydropollinastanol (4,4-desmethyl-5α-cycloart-24-en-3β-ol) and cyclolaudenol [(24S)-24-methyl-5α-cycloart-25(27)-en-3β-ol] have shown the solution conformation of the B/C rings to be...

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Bibliographic Details
Main Authors: Nes, W. David, Benson, Mabry, Lundin, Robert E., Le, Phu H.
Format: Artigo
Language:Inglês
Published: 1988
Subjects:
Physical Sciences: Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC281844/
https://ncbi.nlm.nih.gov/pubmed/16593969
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