Relevance of the reaction of a manganese(III) chelate with hydroxide ion to photosynthesis: Reaction of hydroxide ion with 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphinatomanganese(III) in ligating and nonligating solvents

The reaction of HO(-) with 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphinatomanganese(III) chloride [(TMP)Mn(III)(Cl)] in ligating solvents (CH(3)CN, dimethyl sulfoxide, pyridine) results in formation of (TMP)Mn(II) (≈10(6) M(-1)·s(-r)), which in a slower reaction is converted to a product whose...

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Cyhoeddwyd yn:	Proc Natl Acad Sci U S A
Prif Awduron:	Nakagaki, Paul C., Calderwood, Thomas S., Bruice, Thomas C.
Fformat:	Artigo
Iaith:	Inglês
Cyhoeddwyd:	National Academy of Sciences 1988
Pynciau:	Biological Sciences: Biochemistry
Mynediad Ar-lein:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC281769/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16593963/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.85.15.5424
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