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Saddle-shaped tetraphenylenes with peripheral gallic esters displaying columnar mesophases

Tetraphenylenes 2 with eight peripheral gallic esters were prepared in two steps from octamethoxytetraphenylene 1 in 19–72% yield. Investigation of the mesomorphic properties of 2 by DSC, POM and X-ray diffraction revealed that derivatives 2a–d with short alkoxy chain lengths (C(5)–C(8)) did not sho...

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Detalhes bibliográficos
Main Authors: Wuckert, Eugen, Hägele, Constanze, Giesselmann, Frank, Baro, Angelika, Laschat, Sabine
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2813710/
https://ncbi.nlm.nih.gov/pubmed/20126633
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.5.57
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