Carboxylate as the Protonation Site in (Peroxo)diiron(III) Model Complexes of Soluble Methane Monooxygenase and Related Diiron Proteins

[Image: see text] Addition of H(+) to a synthetic (µ-1,2-peroxo)diiron(III) model complex results in protonation of a carboxylate rather than the peroxo ligand. This conclusion is based on spectroscopic evidence from UV-vis, (57)Fe Mössbauer, resonance Raman, infrared, and (1)H/(19)F NMR studies. Th...

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Hauptverfasser: Do, Loi H., Hayashi, Takahiro, Moënne-Loccoz, Pierre, Lippard, Stephen J.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2010
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2812653/
https://ncbi.nlm.nih.gov/pubmed/20055391
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909718f
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