Modeling the Syn-Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N-Donor Ligand H(2)BPG(2)DEV

In order to model the syn disposition of histidine residues in carboxylate-bridged non-heme diiron enzymes, we prepared a new dinucleating ligand, H(2)BPG(2)DEV, that provides this geometric feature. The ligand incorporates biologically relevant carboxylate functionalities, which have not been explo...

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Bibliografiska uppgifter
Huvudupphovsmän: Friedle, Simone, Kodanko, Jeremy J., Morys, Anna J., Hayashi, Takahiro, Moënne-Loccoz, Pierre, Lippard, Stephen J.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2009
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2758929/
https://ncbi.nlm.nih.gov/pubmed/19757795
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906137y
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