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Palladium-Catalyzed Hydroalkylation of Styrenes with Organozinc Reagents to Form Carbon-Carbon sp(3)-sp(3) Bonds under Oxidative Conditions

An unconventional route for the formation of sp(3)-sp(3) C-C bonds from various styrene and an organozinc reagents in a formal alkene hydroalkylation process is detailed. Mechanistically this process is proposed to proceed by initial transmetallation followed formation of a Pd-H which is subsequentl...

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Detalhes bibliográficos
Main Authors: Urkalan, Kaveri Balan, Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2794962/
https://ncbi.nlm.nih.gov/pubmed/19929001
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja908545b
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