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Total Synthesis and Stereochemical Assignment of (–)-Ushikulide A
We report the determination of the full stereostructure of (–)-ushikulide A (1), a spiroketal containing macrolide by total synthesis. Ushikulide A (1) was isolated from a culture broth of Streptomyces sp. IUK-102 and exhibits potent immunosuppressant activity (IC(50) = 70 nM). To embark upon an ush...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2791109/ https://ncbi.nlm.nih.gov/pubmed/19775093 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906056v |
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