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Bifurcations on Potential Energy Surfaces of Organic Reactions

A single transition state may lead to multiple intermediates or products if there is a post-transition state reaction path bifurcation. These bifurcations arise when there are sequential transition states with no intervening energy minimum. For such systems, the shape of the potential energy surface...

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Autori principali: Ess, Daniel H., Wheeler, Steven E., Iafe, Robert G., Xu, Lai, Çelebi-Ölçüm, Nihan, Houk, K. N.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2008
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2790825/
https://ncbi.nlm.nih.gov/pubmed/18767086
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200800918
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