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EPR Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide Free Radicals in Liquids 6. Separating Line Broadening due to Spin Exchange and Dipolar Interactions
EPR spectra of perdeuterated 2,2,6,6-tetramethyl-4-oxopiperidine-1-oxyl (PDT) are studied as functions of molar concentration, c, and temperature, T, in water and 70 wt% glycerol in water. The increase of the intrinsic linewidth averaged over the three hyperfine lines, 〈B(tot)〉, varies linearly with...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2790056/ https://ncbi.nlm.nih.gov/pubmed/19385676 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp8093947 |
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