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(18)O Kinetic Isotope Effects in Non-Heme Iron Enzymes: Probing the Nature of Fe/O(2) Intermediates
Reported here are the competitive (18)O/(16)O kinetic isotope effects ((18)O KIEs) on k(cat)/K(m)(O(2)) for three non-heme iron enzymes that activate O(2) at an iron center coordinated by a 2-His-1-carboxylate facial triad: taurine dioxygenase (TauD), S-(2)-hydroxypropylphosphonic acid epoxidase (Hp...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2788235/ https://ncbi.nlm.nih.gov/pubmed/18540575 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja800265s |
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