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Catalytic Carbonyl Allylation, Propargylation and Vinylation from the Alcohol or Aldehyde Oxidation Level via C-C Bond Forming Hydrogenation and Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

Classical protocols for carbonyl allylation, propargylation and vinylation typically rely upon the use of preformed allyl metal, allenyl metal and vinyl metal reagents, respectively, mandating stoichiometric generation of metallic byproducts. Through transfer hydrogenative C-C coupling, carbonyl add...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Bower, John F., Kim, In Su, Patman, Ryan L., Krische, Michael J.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2775511/
https://ncbi.nlm.nih.gov/pubmed/19040235
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200802938
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