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Electronic and Steric Effects in Binding of Deep Cavitands
[Image: see text] A deep, self-folding cavitand responds to minor electronic differences between suitably sized adamantane guests. Binding constants range from <0.5 to 4000 M(-1) for guests as similar as 1-bromoadamantane and 1-cyanoadamantane. The barriers to guest exchange also vary up to 3 kca...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2765558/ https://ncbi.nlm.nih.gov/pubmed/18989966 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8022775 |
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