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X-ray emission spectroscopy to study ligand valence orbitals in Mn coordination complexes

We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in x-ray emission spectra that arise from transitions between valence orbitals and t...

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Detalhes bibliográficos
Main Authors: Smolentsev, Grigory, Soldatov, Alexander V, Messinger, Johannes, Merz, Kathrin, Weyhermüller, Thomas, Bergmann, Uwe, Pushkar, Yulia, Yano, Junko, Yachandra, Vittal K., Glatzel, Pieter
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2752666/
https://ncbi.nlm.nih.gov/pubmed/19663435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808526m
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