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Cross-Coupling of Aromatic Bromides with Allylic Silanolate Salts

The sodium salts of allyldimethylsilanol and 2-butenyldimethylsilanol undergo palladium-catalyzed cross-coupling with a wide variety of aryl bromides to afford allylated and crotylated arenes. The coupling of both silanolates required extensive optimization to deliver the expected products in high y...

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Hlavní autoři: Denmark, Scott E, Werner, Nathan S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2748729/
https://ncbi.nlm.nih.gov/pubmed/18998687
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja805951j
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