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Cross-Coupling of Aromatic Bromides with Allylic Silanolate Salts
The sodium salts of allyldimethylsilanol and 2-butenyldimethylsilanol undergo palladium-catalyzed cross-coupling with a wide variety of aryl bromides to afford allylated and crotylated arenes. The coupling of both silanolates required extensive optimization to deliver the expected products in high y...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2008
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2748729/ https://ncbi.nlm.nih.gov/pubmed/18998687 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja805951j |
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