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Charge Asymmetries in Hydration of Polar Solutes

We study the solvation of polar molecules in water. The center of water's dipole moment is offset from its steric center. In common water models, the Lennard-Jones center is closer to the negatively charged oxygen than to the positively charged hydrogens. This asymmetry of water's charge s...

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Detalhes bibliográficos
Main Authors: Mobley, David L., Barber, Alan E., Fennell, Christopher J., Dill, Ken A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2745216/
https://ncbi.nlm.nih.gov/pubmed/18251538
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp709958f
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