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On the fluctuations that drive small ions toward, and away from, interfaces between polar liquids and their vapors
Contrary to the expectations from classic theories of ion solvation, spectroscopy and computer simulations of the liquid–vapor interface of aqueous electrolyte solutions suggest that ions little larger than a water molecule can prefer to reside near the liquid's surface. Here we advance the vie...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2009
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2741216/ https://ncbi.nlm.nih.gov/pubmed/19720991 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0905168106 |
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