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Synthesis and Antioxidant Properties of an Unnatural Plasmalogen Analogue Bearing a trans O-Vinyl Ether Linkage

[Image: see text] To assess the antioxidant behavior of trans-1, we first synthesized trans-allyl ether 4 by opening an (S)-glycidol derivative with an (E)-alk-2-en-ol, and then produced the unnatural E-enol ether 1 by a stereoselective iridium(I)-catalyzed olefin isomerization. Natural cis-1 was pr...

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Detalhes bibliográficos
Main Authors: Lankalapalli, Ravi S., Eckelkamp, Joseph T., Sircar, Debajit, Ford, David A., Subbaiah, Papasani V., Bittman, Robert
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2741175/
https://ncbi.nlm.nih.gov/pubmed/19499908
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9009078
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