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Fundamental Reaction Mechanism and Free Energy Profile for (−)-Cocaine Hydrolysis Catalyzed by Cocaine Esterase

Fundamental reaction mechanism of cocaine esterase (CocE)-catalyzed hydrolysis of (−)-cocaine and the corresponding free energy profile have been studied by performing pseudobond first-principle quantum mechanical/molecular mechanical (QM/MM)-free energy (FE) calculations. Based on the QM/MM-FE resu...

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Autores principales: Liu, Junjun, Hamza, Adel, Zhan, Chang-Guo
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
Materias:
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2738781/
https://ncbi.nlm.nih.gov/pubmed/19642701
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja903990p
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