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Exploring the origin of the internal rotational barrier for molecules with one rotatable dihedral angle

Continuing our recent endeavor, we systematically investigate in this work the origin of internal rotational barriers for small molecules using the new energy partition scheme proposed recently by one of the authors [S. B. Liu, J. Chem. Phys. 126, 244103 (2007)], where the total electronic energy is...

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Detalhes bibliográficos
Main Authors: Liu, Shubin, Govind, Niranjan, Pedersen, Lee G.
Formato: Artigo
Idioma:Inglês
Publicado em: American Institute of Physics 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2736579/
https://ncbi.nlm.nih.gov/pubmed/19044862
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.2976767
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