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A Nonafluoro Nucleoside as a Sensitive (19)F NMR Probe of Nucleic Acid Conformation
[Image: see text] A nucleoside carrying a perfluorinated tert-butyl group (4) was prepared by a Sonogashira coupling of 5-iodo-2′-deoxyuridine with 4,4,4-trifluoro-3,3-is(trifluoromethyl)-1-butyne in nearly quantitative yield and subsequently incorporated into DNA oligomers. Thermal denaturation stu...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2735265/ https://ncbi.nlm.nih.gov/pubmed/18533676 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800872a |
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