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Functional Group Compatibility. Propargyl Alcohol Reduction in the Presence of a Vinyl Iodide

[Image: see text] Vinyl iodides are stable to the reduction of propargyl alcohols to cis allylic alcohols by hydrogen over Pd/CaCO(3) in hexane. They are also stable to the reduction of propargyl alcohols to saturated alcohols by hydrogen over Crabtree’s iridium catalyst in CH(2)Cl(2).

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Detalles Bibliográficos
Autores principales: Denton, Richard W., Parker, Kathlyn A.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
Materias:
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2726658/
https://ncbi.nlm.nih.gov/pubmed/19476372
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900927a
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