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Mechanisms of Peroxynitrite Mediated Nitration of Tyrosine

The mechanisms of tyrosine nitration by peroxynitrous acid or nitrosoperoxycarbonate were investigated with the CBS-QB3 method. Either the protonation of peroxynitrite, or a reaction with carbon dioxide gives a reactive peroxide intermediate. Peroxynitrous acid mediated nitration of phenol occurs vi...

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Detalhes bibliográficos
Main Authors: Gunaydin, Hakan, Houk, K. N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2712443/
https://ncbi.nlm.nih.gov/pubmed/19374346
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx800463y
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