Asymmetric Synthesis of Seven- Membered Carbocyclic Rings via a Sequential Oxyanionic 5-Exo Dig Cyclization/Claisen Rearrangement Process. Total Synthesis of (−)-Frondosin B

[Image: see text] Appropriately substituted nonracemic allyl alcohols, readily prepared from the corresponding enones by application of the CBS methodology, were converted to optically active cycloheptenone derivatives with almost complete transfer of chirality via an efficient “one-pot”, cycloisome...

Full description

Saved in:
Bibliographic Details
Main Authors: Ovaska, Timo V., Sullivan, Jonathan A., Ovaska, Sami I., Winegrad, Jacob B., Fair, Justin D.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2711515/
https://ncbi.nlm.nih.gov/pubmed/19514798
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900967j
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items