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Discrete stack of an odd number of polarized aromatic compounds revealing the importance of net vs. local dipoles

Three polarized aromatic guest molecules (pyrene-4,5-dione, 1) form a triple-layered stack in the box-shaped cavity of an organic pillared coordination cage in water. The cavity size strictly limits the number of stacked planar guests but does not restrict guest orientation, and thus enables the stu...

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Detalhes bibliográficos
Main Authors: Yamauchi, Yoshihiro, Yoshizawa, Michito, Akita, Munetaka, Fujita, Makoto
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2705606/
https://ncbi.nlm.nih.gov/pubmed/19282475
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0810319106
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