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Supramolecular polymer formed by reversible self-assembly of tetrakisporphyrin

S-shaped tetrakisporphyrin 2 forms supramolecular polymeric assemblies via a complementary affinity of its bisporphyrin units in solution. The self-association constant determined by applying the isodesmic model is >10(6) L mol(−1), which suggests that a sizable polymer forms at millimolar concen...

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Hlavní autoři: Haino, Takeharu, Fujii, Takashi, Watanabe, Akihide, Takayanagi, Urara
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2705564/
https://ncbi.nlm.nih.gov/pubmed/19289843
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0809602106
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