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Optical signatures of molecular dissymmetry: Combining theory with experiments to address stereochemical puzzles

Modern chemistry emerged from the quest to describe the three-dimensional structure of molecules: van’t Hoff’s tetravalent carbon placed symmetry and dissymmetry at the heart of chemistry. In this Account, we explore how modern theory, synthesis, and spectroscopy can be used in concert to elucidate...

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Bibliographic Details
Main Authors: Mukhopadhyay, Parag, Wipf, Peter, Beratan, David N.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2704476/
https://ncbi.nlm.nih.gov/pubmed/19378940
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ar8002859
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