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Intramolecular thermal allenyne [2 + 2] cycloadditions; facile construction of the 5-6-4 ring core of sterpurene

A variety of 1-allenyl-2-propargyl-substituted cyclopentanol derivatives were found to undergo facile intramolecular microwave-assisted 2+2 alleneyne cycloaddition reactions to generate tricyclic 5-6-4 ring systems present in the sterpurenes.

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Sonraí Bibleagrafaíochta
Main Authors: Ovaska, Timo V., Kyne, Robert E.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2008
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2701690/
https://ncbi.nlm.nih.gov/pubmed/19562093
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2007.11.042
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