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An exceptionally simple and efficient synthesis of 6-methyl-6-vinylfulvene, and its oxidative transformations

A new efficient synthesis of 6-methyl-6-vinylfulvene was developed, starting from the 6-(2-hydroxyethyl)-6-methylfulvene. With larger quantities of the title compound in hand, its photooxygenation with singlet oxygen was studied. Cyclization of the cyclopropanone intermediate to both vinyl moieties...

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Hlavní autoři: Erden, Ihsan, Gärtner, Christian
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2700951/
https://ncbi.nlm.nih.gov/pubmed/20161263
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.02.221
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