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Deuterium isotope effects on (15)N backbone chemical shifts in proteins
Quantum mechanical calculations are presented that predict that one-bond deuterium isotope effects on the (15)N chemical shift of backbone amides of proteins, (1)Δ(15)N(D), are sensitive to backbone conformation and hydrogen bonding. A quantitative empirical model for (1)Δ(15)N(D) including the back...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Springer Netherlands
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2697368/ https://ncbi.nlm.nih.gov/pubmed/19455282 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s10858-009-9316-0 |
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