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Stereocontrolled Synthesis of D- and L-β-Rhamnopyranosides with 4-O-6-S-α-Cyanobenzylidene-Protected 6-Thiorhamnopyranosyl Thioglycosides

The synthesis of both enantiomers of a 4-O-6-S-α-cyanobenzylidene-protected 6-thio-rhamnopyranosyl thioglycoside is described starting from d-mannnose and l-arabinose derivatives for the d- and l-series, respectively. This donor is effective in the preparation of the corresponding β-glycosides using...

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Detalles Bibliográficos
Main Authors: Crich, David, Li, Linfeng
Formato: Artigo
Idioma:Inglês
Publicado: 2009
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2696688/
https://ncbi.nlm.nih.gov/pubmed/19132946
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo8022439
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