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New Insights into the Detection of Sulfur Trioxide Anion Radical by Spin Trapping: Radical Trapping versus Nucleophilic Addition

It has recently been proposed that (bi)sulfite (hydrated sulfur dioxide) reacts with 5,5-dimethyl-1-pyrroline N-oxide (DMPO) in biological systems via a nonradical, nucleophilic reaction, implying that the radical adduct (DMPO/(•)SO(3)(−)) formation in these systems is an artifact and not the result...

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Detalhes bibliográficos
Main Authors: Ranguelova, Kalina, Mason, Ronald P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2694230/
https://ncbi.nlm.nih.gov/pubmed/19362142
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.freeradbiomed.2009.04.006
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