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Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives

This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.

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Détails bibliographiques
Auteurs principaux: Rowlands, Gareth J, Seacome, Richard J
Format: Artigo
Langue:Inglês
Publié: Beilstein-Institut 2009
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2686273/
https://ncbi.nlm.nih.gov/pubmed/19478964
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.5.9
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