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The Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-based Olefin Metathesis

A series of ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene (NHC) ligands with varying degrees of backbone and N-aryl substitution have been prepared. These complexes show greater resistance to decomposition through C–H activation of the N-aryl group, resulting in increased cata...

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Detalhes bibliográficos
Main Authors: Kuhn, Kevin M., Bourg, Jean-Baptiste, Chung, Cheol K., Virgil, Scott C., Grubbs, Robert H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2679506/
https://ncbi.nlm.nih.gov/pubmed/19351207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900067c
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