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Gold(I)-catalyzed synthesis of (1E,3E)-dienes from propargylic esters
A mild and stereoselective gold(I)-catalyzed domino transformation of propargylic esters leading to substituted (1E,3E)-dienes has been developed. This cascade process proceeds via a sequence of 1,3-acyloxy- or 1,3-phosphatyloxy migrations to form allenic intermediate followed by a proton transfer.
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| Main Authors: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2009
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2678727/ https://ncbi.nlm.nih.gov/pubmed/20161695 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2008.08.010 |
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