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Infrared Spectroscopy of Cationized Arginine in the Gas Phase: Direct Evidence for the Transition from Nonzwitterionic to Zwitterionic Structure

The gas-phase structures of protonated and alkali metal cationized arginine (Arg) and arginine methyl ester (ArgOMe) are investigated with infrared spectroscopy and ab initio calculations. Infrared spectra, measured in the hydrogen-stretch region, provide compelling evidence that arginine changes fr...

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Main Authors: Bush, Matthew F., O'Brien, Jeremy T., Prell, James S., Saykally, Richard J., Williams, Evan R.
Format: Artigo
Jezik:Inglês
Izdano: 2007
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2675882/
https://ncbi.nlm.nih.gov/pubmed/17249666
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja066335j
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