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Structure and mechanism of Cu- and Ni-substituted analogs of metallo-β-lactamase L1
In an effort to further probe metal binding to metallo-β-lactamase L1 (mβl L1), Cu- (Cu-L1) and Ni-substituted (Ni-L1) L1 were prepared and characterized by kinetic and spectroscopic studies. Cu-L1 bound 1.7 equivalents of Cu and small amounts of Zn(II) and Fe. The EPR spectrum of Cu-L1 exhibited tw...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2671888/ https://ncbi.nlm.nih.gov/pubmed/19228020 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi802295z |
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