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TESOTf-Induced Rearrangement of Quinols. Efficient Construction of the Fully Functionalized Carbon Skeleton of the Griseusins by a Divergent-Reconvergent Approach
[Image: see text] The “reverse polarity” or “umpolung” strategy for the total synthesis of aryl C-glycosides was developed in the context of the antibiotic (−)-griseusin B. Although a key reaction in a model sequence for the total synthesis produced two structurally divergent products, both were con...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2668545/ https://ncbi.nlm.nih.gov/pubmed/16623544 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060206q |
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