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Electronically stabilized versions of the antimalarial acetal trioxanes artemether and artesunate

[Image: see text] From 9-substituted DHA, several new artemisinin-derived C-10 acetal ethers and esters were prepared with either a 9-fluoro or a 9-sulfonyl substituent. The very strong inductive electron-withdrawing C-9 substituent is shown to retard considerably C-10 ionization (acid-promoted ethe...

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Bibliographic Details
Main Authors: Posner, G.H., Maio, William A., Kalinda, Alvin S.
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2668193/
https://ncbi.nlm.nih.gov/pubmed/18353653
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmc.2008.03.010
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