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(13)C NMR Characterization of an Exchange Reaction between CO and CO(2) Catalyzed by Carbon Monoxide Dehydrogenase

[Image: see text] Carbon monoxide dehydrogenase (CODH) catalyzes the reversible oxidation of CO to CO(2) at a nickel−iron−sulfur cluster (the C-cluster). CO oxidation follows a ping-pong mechanism involving two-electron reduction of the C-cluster followed by electron transfer through an internal ele...

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Detalhes bibliográficos
Main Authors: Seravalli, Javier, Ragsdale, Stephen W.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2008
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2664834/
https://ncbi.nlm.nih.gov/pubmed/18589895
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi8004522
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