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Doubly hybrid density functional for accurate descriptions of nonbond interactions, thermochemistry, and thermochemical kinetics

We develop and validate a density functional, XYG3, based on the adiabatic connection formalism and the Görling–Levy coupling-constant perturbation expansion to the second order (PT2). XYG3 is a doubly hybrid functional, containing 3 mixing parameters. It has a nonlocal orbital-dependent component i...

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Hlavní autoři: Zhang, Ying, Xu, Xin, Goddard, William A.
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2664054/
https://ncbi.nlm.nih.gov/pubmed/19276116
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0901093106
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